Reason: Androgyny isn't strictly ambiguous gender, but also (and, at least from my knowledge, used more often to describe) a melding of male and female physical traits that have nothing to do with genitalia; tomboyish women, feminine (girly) men, for two examples. I bring this up because I was looking at https://e621.net/post/show/393038 and, while the kobolds depicted are neuter (and I have tagged it as such) some exhibit a slightly more feminine form, others a slightly more masculine form, of which I would call them androgynous- of mixed male and female characteristics.
For images like https://e621.net/post/show/394484 ambiguous_gender still is appropriate, since it is more specifically hiding what traits could identify it as male or female or neuter. https://e621.net/post/show/393658 the same, since we cannot tell the gender of the character in the shadows in the background.
Comparatively, https://e621.net/post/show/393510 we can see no breasts, but we can also clearly see no balls or shaft; typical mammalian-breast-less avian female, but looks a bit masculine. Neuter doesn't apply, but androgynous would.
https://e621.net/post/show/393510 showcases a feline whose genitalia are hidden, a rather masculine face, with rather feminine hips (likely because of the feline aspect). This character is androgynous, AND ambiguously gendered.
https://e621.net/post/show/391440 here we see two males (their penii are very flagrantly in view), with the one being pinned to the lockers showing a very feminine set of facial features, and even cross-dressing.
Girly should imply Androgynous. Androgyny should be aliased to Androgynous. Tomboy should be implying Androgynous as well. Ambiguous_Gender should be separate, and should be used in those cases where gender cannot be told, Androgynous should be used for instances of mixed male/female physical traits, and can thus appear on images together or separately.
Updated